【单选题】
[2]直揍碘量法应控制的条件是___。
A. 强酸性条件
B. 强碱性条件
C. 中性或弱酸性条件
D. 什么条件都可以
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答案
C
解析
暂无解析
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【单选题】
[2]下列关于硫酸铈法的说法不正确的是___。
A. 硫酸铈标准溶液可直接配制
B. Ce4+被还原为Ce3+,只有一个电子转移,不生成中间价态产物
C. 在酸度低于Imol/L时,磷酸对测定无干扰
D. 可在盐酸介质中直接滴定Fe2+,Cl-无影响
【单选题】
[2]标定KMnO4时,第1滴加入没有褪色以前,不能加入第2滴,加入几滴后,方可加快滴定速度原因是___。
A. KMnO4自身是指示剂,待有足够KMnO4时才能加快滴定速度
B. O2为该反应催化剂,待有足够氧时才能加快滴定速度
C. Mn2+为该反应催化剂,待有足够Mn2+才能加快滴定速度
D. MnO2为该反应催化剂,待有足够MnO2才能加快滴定速度
【单选题】
[2]软锰矿主要成分是MnO2,测定方法是过量Na2C2O4与试样反应后,用KMnO4标准溶液返滴定过剩的C2O42-,然后求出MnO2含量。不用还原剂标准溶液直接滴定的原因是___。
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B. 没有合适指示剂
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【单选题】
[2]在酸性介质中,周KMnO4溶液滴定草酸盐溶液时,滴定应___。
A. 像酸碱滴定那样快速进行
B. 始终缓慢地进行
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D. 开始时快,然后减慢
【单选题】
Ce4+滴定Fe2+时,最适宜的指示剂为___。
A. 二苯胺磺酸钠(φθ′㏑=0.84V)
B. 邻苯胺基苯甲酸(φθ′㏑=0.89V)
C. 邻二氮菲-亚铁(φθ′㏑=1.06V)
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【单选题】
[2]用Na2C2O4标定高锰酸钾中,刚开始时褪色较慢,但之后褪色变快的原因是___。
A. 温度过低
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C. Mn2+催化作用
D. 高锰酸钾浓度变小
【单选题】
[2]在酸性介质中,用KMnO4溶液滴定草酸盐溶液,滴定应___。
A. 在室温下进行
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【单选题】
[2]在拟定氧化还原滴定滴定操作中,不属于滴定操作应涉及的问题是___。
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[2]碘量法测定CuSO4含量,试样溶液中加入过量的KI,下列叙述其作用错误的是___。
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C. 与Cu+形成CuI沉淀
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【单选题】
[2] Pb2+ +Sn=Pb + Sn2+反应,已知EθPb2+/Pb=-0.13V、φθSn2+/Sn= -0.14V,在标准状态下,反应向___进行,当[Pb2+] =0.50mol/L时,反应又向( )进行。
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