【单选题】
[2]直揍碘量法应控制的条件是___。
A. 强酸性条件
B. 强碱性条件
C. 中性或弱酸性条件
D. 什么条件都可以
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答案
C
解析
暂无解析
相关试题
【单选题】
[2]在间接碘量法中,若酸度过强,则会有___产生。
A. SO2
B. S
C. SO2和S
D. H2S
【单选题】
[2]在碘量法中,淀粉是寺属指示剂,当溶液呈蓝色时,这是___。
A. 碘的颜色
B. I-的颜色
C. 游离碘与淀粉生成物的颜色
D. I-与淀粉生成物的颜色
【单选题】
[3]自动催化反应的犄点是反应速率___。
A. 快
B. 慢
C. 慢→快
D. 快→慢
【单选题】
[2]下列几种标准溶液一般采用直接法配制的是___。
A. KMnO4标准溶液
B. I2标准溶液
C. K2Cr2O7标准溶液
D. Na2S2O3标准溶液
【单选题】
[2]下列关于硫酸铈法的说法不正确的是___。
A. 硫酸铈标准溶液可直接配制
B. Ce4+被还原为Ce3+,只有一个电子转移,不生成中间价态产物
C. 在酸度低于Imol/L时,磷酸对测定无干扰
D. 可在盐酸介质中直接滴定Fe2+,Cl-无影响
【单选题】
[2]标定KMnO4时,第1滴加入没有褪色以前,不能加入第2滴,加入几滴后,方可加快滴定速度原因是___。
A. KMnO4自身是指示剂,待有足够KMnO4时才能加快滴定速度
B. O2为该反应催化剂,待有足够氧时才能加快滴定速度
C. Mn2+为该反应催化剂,待有足够Mn2+才能加快滴定速度
D. MnO2为该反应催化剂,待有足够MnO2才能加快滴定速度
【单选题】
[2]软锰矿主要成分是MnO2,测定方法是过量Na2C2O4与试样反应后,用KMnO4标准溶液返滴定过剩的C2O42-,然后求出MnO2含量。不用还原剂标准溶液直接滴定的原因是___。
A. 没有合适还原剂
B. 没有合适指示剂
C. 由于MnO2是难溶物质,直接滴定不适宜
D. 防止其他成分干扰
【单选题】
[2]在酸性介质中,周KMnO4溶液滴定草酸盐溶液时,滴定应___。
A. 像酸碱滴定那样快速进行
B. 始终缓慢地进行
C. 在开始时缓慢,以后逐步加快,近终点时又减慢滴定速度
D. 开始时快,然后减慢
【单选题】
[3]下列氧化还原滴定指示剂属于专属的是___。
A. 二苯胺磺酸钠
B. 次甲基蓝
C. 淀粉溶液
D. 高锰酸钾
【单选题】
Ce4+滴定Fe2+时,最适宜的指示剂为___。
A. 二苯胺磺酸钠(φθ′㏑=0.84V)
B. 邻苯胺基苯甲酸(φθ′㏑=0.89V)
C. 邻二氮菲-亚铁(φθ′㏑=1.06V)
D. 硝基邻二氮菲-亚铁(φθ′㏑=1.25V)
【单选题】
[2]用Na2C2O4标定高锰酸钾中,刚开始时褪色较慢,但之后褪色变快的原因是___。
A. 温度过低
B. 反应进行后,温度升高
C. Mn2+催化作用
D. 高锰酸钾浓度变小
【单选题】
[2]为减小间接碘量法的分析误差,下面哪些方法不适用___。
A. 开始慢摇快滴,终点快摇慢滴
B. 反应时放置于暗处
C. 加入催化剂
D. 在碘量瓶中进行反应和滴定
【单选题】
[2]下列几种标准溶液一般采用直接法配制的是___。
A. KMnO4标准溶液
B. I2标准溶液
C. K2Cr2O7标准溶液
D. Na2S2O3标准溶液
【单选题】
[3]标定Na2S2O3溶液的基准试剂是___。
A. Na2 C2 04
B. (NH4)2C2O4
C. Fe
D. K2CrO7
【单选题】
[2]在酸性介质中,用KMnO4溶液滴定草酸盐溶液,滴定应___。
A. 在室温下进行
B. 将溶液煮沸后即进行
C. 将溶液煮沸,冷至85℃进行
D. 将溶液加热到75~85℃时进行
【单选题】
[2]在能斯特方程式的物理量中,既可能是正值,又可能是负值的是___。
A. T
B. R
C. n
D. E
【单选题】
[2]在拟定氧化还原滴定滴定操作中,不属于滴定操作应涉及的问题是___。
A. 滴定速度和摇瓶速度的控制
B. 操作过程中容器的选择和使用
C. 共存干扰物的消除
D. 滴定过程中溶剂的选择
【单选题】
[2]碘量法测定CuSO4含量,试样溶液中加入过量的KI,下列叙述其作用错误的是___。
A. 还原Cu2+为Cu+
B. 防止I2挥发
C. 与Cu+形成CuI沉淀
D. 把CuSO4还原成单质Cu
【单选题】
[2] Pb2+ +Sn=Pb + Sn2+反应,已知EθPb2+/Pb=-0.13V、φθSn2+/Sn= -0.14V,在标准状态下,反应向___进行,当[Pb2+] =0.50mol/L时,反应又向( )进行。
A. 左、左
B. 左、右
C. 右、右
D. 右、左
【判断题】
[2]溶液的酸度越高,KMnO4氧化草酸钠的反应进行得越完全,所以用基准草酸钠标定KMn04溶液时,溶液的酸度越高越好
A. 对
B. 错
【判断题】
[3]氧化数在数值上就是元素的化合价
A. 对
B. 错
【判断题】
[2]氧化还原滴定中,影响电势突跃范围大小的主要因素是电对的电势差,而与溶液的浓度几乎无关
A. 对
B. 错
【判断题】
ΨCu2+/Cu和ΨFe3+/Fe的值都不变
A. 对
B. 错
【判断题】
应方向进行
A. 对
B. 错
【判断题】
[2]氧化还原反应次序是电极电位相差最大的两电对先反应
A. 对
B. 错
【判断题】
[2]氧化还原反应中,两电对电极电位差值越大,反应速率越快
A. 对
B. 错
【判断题】
[3]标定KMnO4溶液的基准试剂是碳酸钠
A. 对
B. 错
【判断题】
[2]错KMnO4标准溶液测定MnO2含量,用的是直接滴定法
A. 对
B. 错
【判断题】
KMnO4滴定C2O42-时,必须加热至沸腾才能保证正常滴定
A. 对
B. 错
【判断题】
[2]直接碘量法以淀粉为指示剂滴定时,指示剂须在接近终点时加入,终点是从蓝色变为无色
A. 对
B. 错
【判断题】
[2]用碘量法测定铜盐中铜的含量时,除加入足够过量的KI外,还要加入少量KSCN,其目的是提高滴定的准确度
A. 对
B. 错
【判断题】
[2]间接碘量法要求在暗处静置溶液,是为了防止I-被氧化
A. 对
B. 错
【判断题】
[2]铜锌原电池的符号为(一)Zn对/Zn2+(0.1mol/L)|对Cu2+(0.1mol/L)对Cu(+)
A. 对
B. 错
【判断题】
[2]由于KMnO4性质稳定,可作基准物直接配制成标准溶液
A. 对
B. 错
【判断题】
[2]配制好的KMnO4溶液要盛放在棕色瓶中保护,如果没有棕色瓶应放在避光处保存
A. 对
B. 错
【判断题】
[2]用Na2C2O4标定KMnO4,需加热到70~80℃,在HCl介质中进行
A. 对
B. 错
【判断题】
[2]配制好的Na2S2O3标准溶液应立即用基准物质K2Cr2O7标定
A. 对
B. 错
【判断题】
[3]配制好的Na2S2O3应立即标定
A. 对
B. 错
【判断题】
[3]错KMnO4标准滴定溶液是直接配制的
A. 对
B. 错
【判断题】
[2]用间接碘量法测合金中的Cu含量时由于CuI吸附I2使测定结果偏低
A. 对
B. 错
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