【单选题】
溶液中，则上述电对的电极电位应是___。
A. 0.324V
B. 1.26V
C. 0.144V
D. -0.324V
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答案
A
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【单选题】
[2]利用电极电位可判断氧化还原反应的性质，但它不能判别___。
A. 氧化还原反应速率
B. 氧化还原反应方向
C. 氧化还原能力大小
D. 氧化还原的完全程度
E. 氧化还原的次序
【单选题】
[1]已知(φΘAg+／Ag=0.7995V和AgI的Ksp=9.3×10-17。若在I-保持1.0mol／L溶液中，则上述电对的电极电位应是___。
A. -0.146V
B. 0.146V
C. 0.327V
D. -0.327V
【单选题】
[2]25。C时将铂丝插入Sn4+和Sn2+离子浓度分别为0.1mol/L和0.01mol/L的混合溶液中，电对的电极电势为___V。
A. φo(Sn4+/Sn2+)
B. φo(Sn4+/Sn2+)＋0.05916/2
C. φo(Sn4+/Sn2+)＋0.05916
D. φo(Sn4+/Sn2+)－0.05916/2
【单选题】
[2]在反应5Fe2+ +MnO4-+8 H+=Mn2+ +5Fe3++4H2O中，高锰酸钾的基本单元为___。
A. KMn04
B. 5KMnO4 c．1/8 KMnO4 D.1/3KMnO4
【单选题】
[2]碘量法测定铜盐中铜的含量，利用的反应为：CuSO4+4I-=2CuI↓+I2 , I2+2Na2S2O3→Na2S4O6+2NaI, 则CuSO4与Na2 S2O3的基本单元的关系是___
A. n(1/4 CuSO4）=n(Na2S2O3)
B. n(1/2 CuSO4）=n(Na2S2O3)
C. n(CuSO4）=n(Na2S2O3)
D. n(1/2CuSO4）=n(1/2Na2S2O3)
【单选题】
[1]用高锰酸钾法测定硅酸盐样品中Ca2+的含量。称取样品0.5972g，在一定条件下，将Ca2+沉淀为CaC2O4，过滤，洗涤沉淀，将洗涤的CaC2O4溶于稀硫酸中，用c(KMnO4)=0.05052mol／L的KMnO4标准溶液滴定，消耗25.62mL，硅酸盐中Ca的质量分数为 ___。已知M (Ca)=40.08g／mol。
A. 24.19%
B. 21.72%
C. 48.38%
D. 74.60%
【单选题】
[3]间接碘量法中加入淀粉指示剂的适宜时间是___。
A. 滴定开始时
B. 滴定至近终点，溶液呈浅黄色时
C. 滴定至I3-离子的红棕色褪尽，溶液呈无色时
D. 在标准溶液滴定了近50%时
【单选题】
[3]用KMnO4法测定H2O2，滴定必须在___。
A. 中性或弱酸性介质中
B. c( H2SO4)=1mol/L介质中
C. pH=10氨性缓冲溶液中
D. 强碱性介质中
【单选题】
[2]下列关于硫酸铈法的说法不正确的是___。
A. 硫酸铈标准溶液可直接配制
B. Ce4+被还原为Ce3+，只有一个电子转移，不生成中间价态产物
C. 在酸度低于Imol／L时，磷酸对测定无干扰
D. 可在盐酸介质中直接滴定Fe2+ ，Cl-无影响
【单选题】
[2]标定KMnO4时，第1滴加入没有褪色以前，不能加入第2滴，加入几滴后，方可加快滴定速度原因是___。
A. KMnO4自身是指示剂，待有足够KMnO4时才能加快滴定速度
B. O2为该反应催化剂，待有足够氧时才能加快滴定速度
C. Mn2+为该反应催化剂，待有足够Mn2+才能加快滴定速度
D. MnO2为该反应催化剂，待有足够MnO2才能加快滴定速度
【单选题】
[2]软锰矿主要成分是MnO2，测定方法是过量Na2C2O4与试样反应后，用KMnO4标准溶液返滴定过剩的C2O42-，然后求出MnO2含量。不用还原剂标准溶液直接滴定的原因是___。
A. 没有合适还原剂
B. 没有合适指示剂
C. 由于MnO2是难溶物质，直接滴定不适宜
D. 防止其他成分干扰
【单选题】
[2]在酸性介质中，周KMnO4溶液滴定草酸盐溶液时，滴定应___。
A. 像酸碱滴定那样快速进行
B. 始终缓慢地进行
C. 在开始时缓慢，以后逐步加快，近终点时又减慢滴定速度
D. 开始时快，然后减慢
【单选题】
Ce4+滴定Fe2+时，最适宜的指示剂为___。
A. 二苯胺磺酸钠（φθ′㏑=0.84V）
B. 邻苯胺基苯甲酸（φθ′㏑=0.89V）
C. 邻二氮菲-亚铁（φθ′㏑=1.06V）
D. 硝基邻二氮菲-亚铁（φθ′㏑=1.25V）
【单选题】
[2]用Na2C2O4标定高锰酸钾中，刚开始时褪色较慢，但之后褪色变快的原因是___。
A. 温度过低
B. 反应进行后，温度升高
C. Mn2+催化作用
D. 高锰酸钾浓度变小
【单选题】
[2]在酸性介质中，用KMnO4溶液滴定草酸盐溶液，滴定应___。
A. 在室温下进行
B. 将溶液煮沸后即进行
C. 将溶液煮沸，冷至85℃进行
D. 将溶液加热到75～85℃时进行
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